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All Characters (well, most of the characters) from Undertale (the Pacifist way)
Flowey is the first major character that the protagonist encounters in Undertale, serving as the main antagonist for the majority of the game, specifically the Neutral and Pacifist routes. He provides an introduction to the mechanics of encounters by sharing “friendliness pellets,” which are actually harmful bullets. His main philosophy is “KILL or BE killed.”
Toriel is the second major character the protagonist encounters in Undertale. She saves the protagonist from Flowey and guides them through the Ruins.
Sans is the older brother of Papyrus and a major character in Undertale. He first appears in the forest after the protagonist exits the Ruins. He serves as a supporting character in the Neutral and True Pacifist Route and as the final boss and heroic antagonist in the Genocide Route.
Frisk is the playable character who also serves as the main protagonist of Undertale. After falling into the Underground, Frisk embarks on a journey to return to the Surface. Frisk is the last of the eight humans to fall into the Underground after traveling to Mount Ebott.
Papyrus known as COOLSKELETON95 on UnderNet, is the younger brother of Sans and a major character in Undertale. He wants to capture a human so he can become a member of the Royal Guard.
Undyne known as StrongFish91 on the UnderNet, is a fish-like monster that leads the Royal Guard. Clad in her full suit of armor, she pursues the protagonist through the entirety of Waterfall and is frequently evaded or inadvertently thwarted by the Monster Kid.
Dr. Alphys is a female, reptillian monster that lives in the lab in western Hotland. She is the incumbent Royal Scientist, a position she was awarded by Asgore after the death of her predecessor. Asgore hired Alphys because she told him that she had created a SOUL; in reality, she created a robotic body for a ghost.
Mettaton is a robot with a SOUL and was built by Alphys. Initially poised as an entertainment robot turned human killing robot, Mettaton is later revealed to have only acted as such. Mettaton is the sole television star of the Underground.
King Asgore Dreemurr is the ruler of the Underground and its denizens, monsters. He is the ex-husband of Toriel, father of Asriel Dreemurr, adoptive father of the first human, and the second to final boss of the Neutral Route. While not necessarily evil or malicious, he serves as one of the main antagonists, scheming to kill seven humans and use their SOULs to break the barrier which traps the monsters in the Underground.
Asriel Dreemurr is the biological child of Toriel and Asgore, and the adoptive brother of the fallen human. He serves as the final boss of the True Pacifist route, and the hidden main antagonist of Undertale.
Chara also known as the First Human or the Fallen Human, is the first human to fall into the Underground. This is the human that the player names at the start of the game, and not the controllable character who is played throughout the entirety of Undertale.
Bratty and Catty are a pair of vendors that can be found in an alley to the right of the MTT Resort. They are best friends, often saying the same lines or finishing sentences for each other. They have several wares found from the Garbage Dump, including the Mystery Key.
Napstablook is a melancholic ghost monster and musician who lives in Waterfall, encountered in the Ruins as the game’s first miniboss.
Temmie is a species of monster in the Underground. They appear as a unique enemy in Waterfall, residents of Temmie Village, and the vendor of Tem Shop.
Contrary to popular belief, killing Temmie accrues EXP and is considered a kill by the game, which will cause a True Pacifist Route attempt to fail.
Muffet is the main boss the protagonist encounters in Hotland. She runs a bake sale, being very angry at passers who do not purchase anything from it.